When I was younger, I used to wear stockings every day because I liked them! I still wear them on and off, but was finding it expensive to get really nice ones when I needed a new pair practically every day after travelling on the tube to work and back! They are not uncomfortable if you take care to make sure and buy a size that fits well and a decent suspender belt that is properly adjustable in length and at waist. It IS sexier too, and has always been a turn on for most men.
There is a brand I buy which have a pretty lace top that is ultra glam, and makes you feel really confident and sexy, even though only you (and hubby) will know you are wearing them.
I think it's sweet that your hubby has these kind of thoughts about you

Give him a little of what he fancies, it'll do you both good
Besides, you never know you might like it, and wear them more often for yourself, and if you decide you really hate wearing them, I am sure hubby will understand, and appreciate that you did have a go for him
enjoy!